These provisions are multi-modal and apply to bulk and non-bulk packagings: 1 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone A (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. 165 These substances are susceptible to exothermic decomposition at elevated temperatures. 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. These batteries are typically used for portable power applications. However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. (5) N codes. Column 7 contains special provisions associated with the hazardous material. D. Class 5 materials N41 Metal construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Other inorganic nitrate salts may replace part of the ammonium nitrate. If unlined tanks are washed out with water, they must be repassivated prior to return to service. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate; 5-30% water; 2-8% fuel; 0.5-4% emulsifier or thickening agent; 0-10% soluble flame suppressants; and trace additives. The requirements of 173.24(g)(1) and 173.27(c) do not apply. N86 UN pressure receptacles made of aluminum alloy are not authorized. A100 Lithium ion cells and batteries must be offered for transport at a state of charge not exceeding 30 percent of their rated capacity. 49 U.S.C. Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. Choosing an item from The in-page Table of Contents is available only when multiple sections are being viewed. They must be classified in accordance with the procedure as set out in the Manual of Tests and Criteria, part III, section 39 (IBR, see 171.7 of this subchapter). (2) A code containing the letter A refers to a special provision which applies only to transportation by aircraft. (3) B codes. (9) A code containing the letter W refers to a special provision that applies only to transportation by water. 6. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. N45 Copper cartridges are authorized as inner packagings if the hazardous material is not in dispersion. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. developer resources. Table 1 authorizes IBCs for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. If chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of transport, temperature control is required and is forbidden by aircraft. B16 The lading must be completely covered with nitrogen, inert gas or other inert materials. 420 This entry does not apply to manufactured articles (such as table tennis balls). Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. B27 Tanks must have a service pressure of 1,034 kPa (150 psig). 26 This entry does not include ammonium permanganate, the transport of which is prohibited except when approved by the Associate Administrator. eCFR :: 49 CFR 172.202 -- Description of hazardous material on shipping The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. be marked with the hydrostatic pressure test marking specified in 173.24a(b)(4). This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. Your Nuclear Attack Map for 2023 - mirasafety.com Bulk packagings must have exterior heating coils fusion welded to the tank shell which have been properly stress relieved. 49 CFR 172.101 - Purpose and use of hazardous materials table. (4) A code containing the letters IB or IP refers to a special provision that applies only to transportation in IBCs. TP26 The heating device must be exterior to the shell. B32 MC 312, MC 330, MC 331, DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, then the shipping paper must indicate both UN 3091 Lithium metal batteries packed with equipment and UN 3481 Lithium ion batteries packed with equipment.. 5101-5128, 44701; 49 CFR 1.81, 1.96 and 1.97. Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic liner of at least 6 mil thickness. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. Liquefied compressed gases are assigned to portable tank instruction T50. B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). However this examination is required when the conditions of 180.605(f) are met. 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. TP12 This material is considered highly corrosive to steel. This contact form is only for website help or website suggestions. PDF 171.26 49 CFR Ch. I (10-1-11 Edition) - GovInfo PDF Hazard Classifications Used in Hazmat Table, Column 3 d. In addition to the training requirements prescribed in 172.700 through 172.704, each driver must be trained regarding the properties and hazards of diatomaceous earth filter material, precautions to ensure safe transport of the material, and actions to be taken in the event of an emergency during transportation, or a substantial delay in transit. 137 Cotton, dry; flax, dry; sisal, dry; and tampico fiber, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, Cotton Bales - Dimensions and Density (IBR, see 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax, 620 kg/m3 (38.71 lb/ft3) for sisal and 360 kg/m3 (22.1 lb/ft3) for tampico fiber and transported in a freight container or closed transport vehicle. 58 Aqueous solutions of Division 5.1 inorganic solid nitrate substances are considered as not meeting the criteria of Division 5.1 if the concentration of the substances in solution at the minimum temperature encountered in transport is not greater than 80% of the saturation limit. The Meaning of the Symbols in Column 7 of the Hazardous Materials Table The official, published CFR, is updated annually and available below under B48 Portable tanks in sodium metal service may be visually inspected at least once every 5 years instead of being retested hydrostatically. N78 Packages consisting of inner glass, earthenware, or polyethylene or other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. Regulation Y In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator. Hazardous materials shipped under this entry are excepted from the labeling requirements of this subchapter unless offered for transportation or transported by aircraft and are not subject to the placarding requirements of subpart F of this part. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. N12 Plastic packagings are not authorized. 110 Fire extinguishers transported under UN1044 and oxygen cylinders transported for emergency use under UN1072 may include installed actuating cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per cylinder. For liquids transported under ambient conditions may be calculated using the formula: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. For other than Class 7 or the DANGEROUS . c. Self-propelled vehicles or equipment that also contain an internal combustion engine must be described using the entries Engine, internal combustion, flammable gas powered or Engine, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. Other inorganic nitrate salts may replace part of the ammonium nitrate. FAQ: What are Special Provisions in the USDOT/PHMSA Hazardous Materials The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. B76 Tank cars constructed before March 16, 2009, must have a test pressure of 20.68 Bar (300 psig) or greater and conform to Class 105S, 112J, 114J or 120S. Packagings may include a vent to permit the slow escape of gas (i.e. Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. 132 This description may only be used for ammonium nitrate-based compound fertilizers. Each inner packaging contains not more than 30 mL; b. The material must be loaded dry. In addition, the column 5 reference is modified to read III on those occasions when this material is offered for transportation or transported by highway or rail. 342 Glass inner packagings (such as ampoules or capsules) intended only for use in sterilization devices, when containing less than 30 mL of ethylene oxide per inner packaging with not more than 300 mL per outer packaging, may be transported in accordance with 173.4a of this subchapter, irrespective of the restriction of 173.4a(b) and the indication of forbidden in columns (9A) and (9B) of the 172.101 table provided that: a. N85 Packagings certified at the Packing Group I performance level may not be used. 198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be transported as paint, perfumery products, or printing ink, as applicable, provided the nitrocellulose contains no more 12.6% nitrogen (by dry mass). 166 When transported in non-friable tablet form, calcium hypochlorite, dry, may be transported as a Packing Group III material. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. Codes in Column 7 may be numbers, or a combination of letters and numbers. When such batteries are transported in accordance with 173.185(c), the total lithium content of all lithium metal cells contained in the battery must not exceed 1.5 g and the total capacity of all lithium ion cells contained in the battery must not exceed 10 Wh. 70 Black powder that has been classed in accordance with the requirements of 173.56 of this subchapter may be reclassed and offered for domestic transportation as a Division 4.1 material if it is offered for transportation and transported in accordance with the limitations and packaging requirements of 173.170 of this subchapter. Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in. There you have it! 238 Neutron radiation detectors: Neutron radiation detectors containing non-pressurized boron trifluoride gas in excess of 1 gram (0.035 ounces) and radiation detection systems containing such neutron radiation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the following: a. TP37 IM portable tanks are only authorized for the shipment of hydrogen peroxide solutions in water containing 72% or less hydrogen peroxide by weight. This entry may only be used for the transport of non-activated batteries that contain dry potassium hydroxide and that are intended to be activated prior to use by the addition of an appropriate amount of water to the individual cells. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). b. The Table: provides the proper shipping name or directs the user to the preferred proper shipping name; N5 Glass materials of construction are not authorized for any part of a packaging which is normally in contact with the hazardous material. d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions: (1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see 171.7 of this subchapter); (2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia; (3) Each receptacle shall be able to withstand the pressure generated at 85 C (185 F) with a volumetric expansion no greater than 0.1%; (4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and. Effective January 1, 2012, for transportation by vessel, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. N20 A 5M1 multi-wall paper bag is authorized if transported in a closed transport vehicle. is available with paragraph structure matching the official CFR 35 Antimony sulphides and oxides which do not contain more than 0.5 percent of arsenic calculated on the total mass do not meet the definition of Division 6.1. 39 This substance may be carried under provisions other than those of Class 1 only if it is so packed that the percentage of water will not fall below that stated at any time during transport. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds). N84 The maximum quantity per package is 500 g (1.1 lbs.). In addition, MC 312 and DOT 412 cargo tank motor vehicles must: c. Have a MAWP or design pressure of at least 87 psig; and. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. A191 Notwithstanding the Division 6.1 subsidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the shipping paper are not required for manufactured articles containing less than 5 kg (11 pounds) of mercury. air bag inflators, air bag modules, seat-belt pretensioners, and pyromechanical devices containing Class 1 (explosive) materials or materials of other hazard classes. A82 The quantity limits in columns (9A) and (9B) do not apply to human or animal body parts, whole organs or whole bodies known to contain or suspected of containing an infectious substance. How to Use Hazmat Special Provisions | Lion Technology A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. These notes are explained at the end of each TABLE. The tank car specification may be marked to indicate a test pressure of 20.68 Bar (300 psig). A copy of the approval must accompany each shipment. 173 For adhesives, printing inks, printing ink-related materials, paints, paint-related materials, and resin solutions which are assigned to UN3082, and do not meet the definition of another hazard class, metal or plastic packaging for substances of packing groups II and III in quantities of 5 L (1.3 gallons) or less per packaging are not required to meet the UN performance package testing when transported: a. (6) A code containing the letter R refers to a special provision which applies only to transportation by rail. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. A189 Except where the defining criteria of another class or division are met, concentrations of formaldehyde solution: a. The battery has been tested as a primary lithium battery; and. 172-29, 41 FR 15996, Apr. Except when approved by the Associate Administrator, these items may only contain hazardous materials for which exceptions are referenced in Column (8) of the 172.101 Table and are provided in part 173, subparts D and G, of this subchapter. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. 56 A means to interrupt and prevent detonation of the detonator from initiating the detonating cord must be installed between each electric detonator and the detonating cord ends of the jet perforating guns before the charged jet perforating guns are offered for transportation. PDF Special Provision Letter Codes Used in Hazmat Table, Column 7 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. The Code of Federal Regulations (CFR) is the official legal print publication containing the codification of the general and permanent rules published in the Federal Register by the departments and agencies of the Federal Government.